ADSORPTION PROPERTIES OF HYDROPHOBIC POROUS COORDINATION POLYMERS OF ZINC-OXALIC ACID WITH TRIAZOLE AND AMINO TRIAZOLE MIXTURE LIGANDS

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Moondra Zubir, Zainuddin Muchtar, Jasmidi Jasmidi, Rini Selly, Siti Rahmah, Putri Faradilla, Dikki Miswanda

2024 Chemistry and Chemical Technology Vol. 18 Issue 3 Article Cited by 0

Abstract

The porous coordination polymers were prepared from Zn2+ and oxalic acid with 2 linker ligands, 1,2,4-triazole (Taz) and 3-amino-1,2,4-triazole (ATaz). The adsorption of N2 after adsorption of degassed CO2 in the pore frameworks increased by 3 times. The flexibility of this structure is due to the interaction of CO2 molecules with the amine groups contained in it, thereby increasing its porosity. © Zubir M., Muchtar Z., Jasmidi J., Selly R., Rahmah S., Faradilla P., Miswanda D., 2024.

Affiliations

Chemistry Department, Faculty of Mathematics and Natural Sciences, Universitas Negeri Medan, North Sumatera, Indonesia; Chemistry Department, Faculty of Science, Shinshu University, Nagano, Matsumoto, Japan; Mechanical Engineering Department, Politeknik Negeri Medan, North Sumatera, Medan, Indonesia