Effect of Gd2O3 in Li2O–AlF3–CaF2–P2O5–Eu2O3 glasses for laser medium and X-rays detection material applications

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C.S. Sarumaha, J. Rajagukguk, J. Tongdang, N. Chanthima, H.J. Kim, S. Kothan, J. Kaewkhao

2022 Radiation Physics and Chemistry Vol. 199 Article Cited by 11 Quartile

Abstract

The glass formula of 20Li2O+10AlF3+2.5CaF2+(66.5-x)P2O5+xGd2O3+1Eu2O3 (PLACEu1Gdx), where x = 2,4,6,8,10 mol% have been prepared by conventional melt-quenching technique. These glasses' optical absorption, photoluminescence, decay time, and radioluminescence have been measured at room temperature. Judd-Ofelt's (J-O) analysis of PLACEu1Gd8 has been investigated and the magnitude of parameters follows the trend as Ω2>Ω4>Ω6. The important laser parameters such as radiative properties are calculated using J-O parameters and luminescence spectra. The decay time with the transition from the 5D0 level was estimated under 274 nm and 394 nm excitation using bi-exponential fitting. CIE coordinates, CCT and intensity ratio have been calculated for glass samples. The integral scintillation efficiency of PLACEu1Gd8 is 31% compared with BGO crystal. The PLACEu1Gdx glasses are promising for laser medium and x-rays detection material applications. © 2022 Elsevier Ltd

Affiliations

Physics Program, Faculty of Science and Technology, Nakhon Pathom Rajabhat University, Nakhon Pathom, 73000, Thailand; Center of Excellence in Glass Technology and Materials Science (CEGM), Nakhon Pathom Rajabhat University, Nakhon Pathom, 73000, Thailand; Department of Physics, Faculty of Mathematics and Natural Sciences, Universitas Negeri Medan, Medan, 20221, Indonesia; Department of Physics, Kyungpook National University, Daegu, 41566, South Korea; Center of Radiation Research and Medical Imaging, Department of Radiologic Technology, Faculty of Associated Medical Sciences, Chiang Mai University, Chiang Mai, 50200, Thailand